These elements are characterized by having their differentiating electron enter the (n-2)f orbitals. This placement distinguishes them from the main group elements and transition elements, where the differentiating electron enters s, p, and d orbitals, respectively. As a consequence of this electronic configuration, these elements exhibit unique chemical and physical properties. A clear example is the lanthanide series, often found in applications such as magnets and catalysts, where the filling of the 4 f orbitals influences their magnetic and catalytic behavior.
The significance of these elements lies in their role in various technological applications and fundamental research. Their unique electronic configurations contribute to diverse properties, making them valuable in fields such as nuclear technology, materials science, and catalysis. Historically, the understanding and isolation of these elements posed significant challenges due to their chemical similarities, but advancements in separation techniques have unlocked their potential across numerous industries.