One fundamental principle in chemistry dictates that a chemical compound always contains exactly the same proportion of elements by mass. For instance, water (HO) always consists of two hydrogen atoms and one oxygen atom, regardless of its source. This constancy in composition is described by one key principle. In contrast, another principle addresses situations where two elements can combine to form more than one compound. This principle states that if two elements form more than one compound between them, the ratios of the masses of the second element which combine with a fixed mass of the first element will always be ratios of small whole numbers. An example is nitrogen and oxygen, which form various oxides like NO, NO, NO, NO, and NO. For a fixed mass of nitrogen, the masses of oxygen in these compounds are in simple whole-number ratios.
These principles are cornerstones of stoichiometry and helped lay the groundwork for understanding the atomic nature of matter. Historically, they provided crucial evidence for Dalton’s atomic theory and allowed scientists to determine relative atomic masses. The ability to predict and understand the composition of chemical compounds is essential in various fields, including chemical synthesis, analysis, and understanding chemical reactions. It allows for precise calculations and control over chemical processes, leading to advancements in medicine, materials science, and environmental science.